Chemistry - Inorganic Chemistry and the Periodic Table (Edex

Chemistry
Chemistry

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Front Trends in halogen chemistry
Back As you descend group 7, electronegativity decreases.- increase in sheilding- distance of outer e- from nucleus increases- reduces electrostatic forces of attraction between themHow reactive the element is depends on whether the reaction is causing reduction or oxidation in the halogen.Reduction of group 7 elements decreases down the group. (Reasons analogous to electro-vitiy). Therefore, oxidation of group 7 increases down the group.As few elements, are as electro-ve as group 7 elements, we can predict group 7 atoms are reduced when making compounds.Cl gas    due to increasing number of electrons, stronger londonBr liquid      forces, greater melting and boiling points.I solid        (at standard temperature and pressure.)
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Front Group 2 + water Reaction
Back - not as vigorous as group 1 reaction- rate of reaction increases down groupe.g. Mg(s) + 2H2O(l) --> Mg(OH)2(s) + H2(g)However! Mg(s) + 2H2O(g) --> MgO(s) + H2(g)
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Front Chlorine + cold alkalis
Back disproportionation reactionCl2 + 2NaOH ⇌ NaClO(aq) + NaCl(aq) + H2O(l)                   sodium chlorate (I)/ sodium hypochlorate (bleach)Position of equilibrium far over to the right  If acid is added, OH- is neutralised, shifting equilibrium to the left, producing Cl2 gas (toxic)
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