CHAPTER 1 GENERAL CHEMISTRY

Chemistry
MCAT

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Front True or FalseHalf filled and fully filled d(and f) orbitals tend to have lower energies than other ones and thus are more stable, hence favored
Back TrueNotable examples,Chromium(and other elements in its group)Should have a configuration of [Ar]4s2, 3d4However moving one electron from 4s to 3d allows the 3d to be half filled, which is more stableThus in reality chromium is:[Ar]4s1, 3d5Copper(and other elements in its group)Should have [Ar]4s2,3d9However moving one electron from 4s to 3d allows the 3d to be fully filled, which is more stableThus in reality copper is:[Ar]4s1, 3d10This exception is seen only in d and f orbitals, not seen in p orbitals
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Front Can two electrons of the same atom posses the same quantum numbers
Back NoAccording to the Pauli exclusion principle no two electrons in the same atom can posses the same four quantum numbers
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Front What formula relates energy and frequency
Back E = hfThis is the energy for 1 photonIf given, 600 photon for example, and you know frequency of them, the energy for that sample is E = 600 * hfSince E = hf is for 1 photon, to get the energy for 600, simply multiply the number by 600H = Planck's constant has the value 6.626e-34F = frequency of the radiationE= energy
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